Installed latest Duplicati but can't see it as a service

First thing to check would be snapshot-policy which defaults to off and has multiple versions of enable. Locked file, errors on outlook.pst has some discussion on the finer points of figuring out which setting you want to use.

Migrating from User to Service install on Windows (and elsewhere) has discussion about various service issues, however it sounds like you might not be heading there immediately, so maybe you can migrate when/if needed.